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正版 固化复合吸附剂特性及其在能源转换中的应用(英文版)(精) Li
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1 Introduction
1.1 Solid Sorption Phenomena
1.2 Fundamental Principle of Solid Sorption
1.3 Solid Sorption Working Pairs
1.4 Solid Composite Sorbents with ENG Matrix
1.5 Solid Sorption Theory
1.6 Energy Conversion Cycles of Solid Composite Sorbents
References
2 Development of Solid Composite Sorbents
2.1 Techniques for Processing Natural Graphite
2.1.1 ENG without GIC
2.1.2 ENG-GICs
2.2 Techniques for Developing the Composite Solid Sorbents with ENG
2.2.1 Simple Mixture and Consolidation
2.2.2 Impregnation and Compression
2.3 Techniques for Developing the Composite Solid Sorbents
with Activated Carbon Fiber or Activated Carbon
2.3.1 The Characteristics of Active Carbon Fiber
2.3.2 Composite Sorbent with Activated Carbon Fiber as Matrix
2.3.3 Composite Sorbent with Activated Carbon as Matrix
2.4 Techniques for Developing the Composite Solid Sorbents with Silica Gel
References
3 Properties of Solid Composite Sorbents
3.1 Properties of Consolidated ENG
3.1.1 Anisotropic Thermal Conductivity and Permeability of CENG without GICs
3.1.2 Anisotropic Thermal Conductivity and Permeability of CENG-GICs
3.2 Properties of Composite Solid Sorbents with ENG
3.2.1 The Physical Composite Sorbents
3.2.2 The Chemical Composite Sorbents
3.3 Properties of Composite Solid Sorbents with Activated
Carbon and Activated Carbon Fiber
3.3.1 Composite Solid Sorbents with Activated Carbon
3.3.2 Composite Solid Sorbents with Activated Carbon Fiber
3.4 Properties of Composite Solid Sorbents with Silica Gel
3.4.1 Composite Sorbents of Silica Gel and CaC12
3.4.2 The Composite Sorbent of Silica Gel and LiC1
3.4.3 The Comparison between Activated Carbon Fiber and Silica Gel as Matrix
References
4 Kinetics of Solid Composite Sorbents
4.1 Typical Principles and Phenomena
4.1.1 Clapeyron Equation
4.1.2 Precursor State of Solid Chemisorption in Halide-Ammonia
4.1.3 The Desorption Hysteresis Phenomenon
4.2 Analysis of Five Classical Kinetic Models
4.2.1 An Analogical Model Considering Various Classifications of Kinetic Parameters
4.2.2 An Analogical Model Uncoupling the Kinetic and Thermal Equation
4.2.3 An Analytical Model Based on the Thermophysical Properties of the Reaction Medium
4.2.4 Phenomenological Grain-Pellet Model
4.2.5 A Numerical Model for CHPs
4.3 Sorption Phenomena in Halide-Ammonia Working Pairs Developments in Recent Years
4.3.1 Non-equilibrium Clapeyron Figure
4.3.2 New Discoveries Related to Sorption Hysteresis
4.3.3 Part of the Composite Sorbent Models
4.4 The Development Direction of Kinetic Models for Further Research
References
5 Solid Sorption Cycle for Refrigeration, Water Production, Eliminating NOx Emission and Heat Transfer
5.1 Solid Sorption Cycle for Refrigeration
5.1.1 Single-Stage Solid Sorption Refrigeration Cycle
5.1.2 Two-Stage Chemisorption Cycle with CaCI2/BaCI2-NH3 Working Pair
5.1.3 A MnC12/CaCI2-NH3 Two-Stage Solid Sorption Freezing System for the Refrigerated Truck
5.2 Solid Sorption Cycle for Water Production
5.2.1 Principle of the Cycle and System Design
5.2.2 The Lab System Driven by Electricity
5.2.3 The Test System Driven by Solar Power
5.2.4 Scalable Prototype with Energy Storage Tank
5.3 Solid Sorption Cycle for Eliminating NOx Emission
5.3.1 Working Principle
5.3.2 Theoretical Performance Analysis of Halide-NH3 Chemisorption
5.3.3 Results of Composite Sorbents-NH3
5.4 Solid Sorption Cycle for Heat Transfer
5.4.1 Fundamentals of SSHP
5.4.2 Experimental Setup
5.4.3 Thermal Performance of SSHP
References
6 Solid Sorption Cycle for Energy Storage, Electricity Generation and Cogeneration
6.1 Solid Sorption Cycle for Energy Storage
6.1.1 Establishment of the Heat and Refrigeration Cogeneration Cycle
6.1.2 Performance Analysis
6.1.3 Results and Discussions
6.2 Solid Sorption Cycle for Electricity and Refrigeration Cogeneration
6.2.1 Cogeneration Principle and Theoretical Analysis
6.2.2 Experiment Set-up
6.2.3 Results and Discussions
6.3 Resorption Cycle for Electricity and Refrigeration Cogeneration
6.3.1 Design and Performance Analysis of a Resorption Cogeneration System
6.3.2 An Optimized Chemisorption Cycle for Power Generation
References
Index
化学吸附技术是实现中低温热能转换的有效技术,但较低的导热系数和结块现象极大地影响了其性能。近20年来,研究人员探索了利用导热多孔基质改善其传热传质性能,研究成果所形成的复合固化吸附技术,目前广泛应用于制冷、取水、除NOx、传热和储能等领域。本文综述了固化复合吸附剂的性能和能量转换技术的**进展,包括制备方法、传质传质特性、动力学模型以及不同吸附循环在能量转换中的应用。
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